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UV/O3 UV Ǵ Ǵ Ŀ .

1> UV

UV ڱķμ ִ.
ڱĴ 忡 , ܼ ϰ, ª ڿܼ ܼ̳ ñ ϴ. ڿܼ ª X-̳ ñ ϸ ϴ.
UV 184.9NM 253.7NM ε ִ.

N = N.h.C/ (K Cal/mol)

N : ƺ (6.023*10 23/mol)
h : ÷ũ (6.626 * 10 27 erg.sec).
c : (2.998 * 108m/sec).
: ( nm).

Ŀ 253.7nm Ͽ ϸ 113kcal/mol , 184.9nm Ͽ ϸ 154.7kcal/mol ´.
UV 184.9nm 154.7kcal/mol ̶ Ҽ ּ C-C, C-O, Si-O, SiC, C-H, C-N, O-O, O-H ϰ ִ .
, Ҽ ּ C-C 84.3 kcal/mol ε, 184.9nm UV 154.7kcal/mol ̴. ڱ 2迡 Ƿ(Energy Bombardment) .
ȭ ƴϰ, ڱ Ϸ Bombardment ƴϴ.
, ũ 25mm ö M16 ո 108mm źδ ո Ͱ ġ.
ó ϹǷ Ҽ ȭ κ ȭǾ CO2 ȭǾ ߵȴ. ȭǾ ߵȴٴ ǹ̴ ǥ鿡 ư LCD Ҽ ƹ͵ Ƿ , ǽ ô Ǵ ̴.

Ʒ ǥ ȭ ̴.

ȭ
ȭ
C-C
84.3
O-H
109.3
C-O
76.4
C =C
140.5
Si-O
105.4
C-F
115.2
Si-C
69.8
C-Cl
76.9
C-H
97.6
C=O
190.0
C-N
63.6
O=O
117.5
O-O
32.9
H-F
134.9
H-Cl
101.9
N-H
91.9
253.7nm
113
184.9nm
154.7
- : kcal/mol


2> ȭ

UV 20.9% ̴.
ڰ UV UV Ұ Ȱȭ ȴ.
Ȱȭ Ҵ ڿ Ͽ O3 ȭ ȴ.

O2 + hv O(1D)
O(1D) + O2 O3

O3 ⹰ ۿϿ ȭ Ű⵵ ϰ, ߻ Ұ а ۿϿ OHĮ Į ȭ ۿϱ⵵ Ѵ.

O3 +( CHO) CO2 + H2O
Ҽ
O(1D) + H2O 2HO-
O(1D) + O2 O3